Thank you for your reply.
The mysqldump command executed without any issues and I have done it on several occasions to ensure it terminated well. I have also checked the users in both databases as you suggested and they happen to be the same.
I initially performed a login with two users to eliminate any issues that one user might have but the same problem still occurred and i even performed a "Grant all Privilege" sql command for both users, but the issue still reoccurs.
After login credentials are inserted and i click on login, it shows a blank page with "http://192.168.247.128/sysworkflow/en/neoclassic/login/authentication.php" showing in the address bar. Refreshing the Browser returns the same blank page, however when I click inside the address bar and press enter, it then shows this;